Supplementary Materials: Temporal scaling in information propagations

Estimating IDF based on daily precipitation using temporal scale model

The intensity –duration –frequency (IDF) curves play most important role in watershed management, flood control and hydraulic design of structures. Conventional method for calculating the IDF curves needs hourly rainfall data in different durations which is not extensively available in many regions. Instead 24-hour precipitation statistics were measured in most rain-gauge stations. In this stud...

Temporal switching of an amphiphilic self-assembly by a chemical fuel-driven conformational response† †Electronic supplementary information (ESI) available: Experimental section, synthetic procedures and supporting figures. See DOI: 10.1039/c7sc01730h Click here for additional data file.

The stabilizing effect of shear thinning on the onset of purely elastic instabilities in serpentine microflows† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sm00326e Click here for additional data file.

We determine both experimentally and numerically the onset of elastic flow instabilities in viscoelastic polymer solutions with different levels of shear thinning. Previous experiments realized in microfluidic serpentine channels using dilute polymeric solutions showed that the onset of elastic instabilities strongly depends on the channel curvature. The scaling dependence is well captured by t...

Accelerated Hantzsch electrospray synthesis with temporal control of reaction intermediates† †Electronic supplementary information (ESI) available: Spectra for all on-line, off-line, and substituent studies as well as photographs of experimental setups are supplied. See DOI: 10.1039/c4sc02436b Click here for additional data file.

Linear scaling relationships and volcano plots in homogeneous catalysis – revisiting the Suzuki reaction† †Electronic supplementary information (ESI) available: Detailed derivation of the linear scaling relationships and construction of the volcano plots as well as comparisons of computed values using PBE0-dDsC and M06 functionals is included. See DOI: 10.1039/c5sc02910d Click here for additional data file.

Linear free energy scaling relationships and volcano plots are common tools used to identify potential heterogeneous catalysts for myriad applications. Despite the striking simplicity and predictive power of volcano plots, they remain unknown in homogeneous catalysis. Here, we construct volcano plots to analyze a prototypical reaction from homogeneous catalysis, the Suzuki cross-coupling of ole...